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●Formate adsorption/desorption is just an individual process which occurs in parallel with HCOOH oxidation.

●HCOOad limits the surface sites for HCOOH oxidation.

●Phys. Chem. Chem. Phys., 2013, 15 (12), 4367

 

●Chen et al., 2006. Bridge-bonded formate: Active intermediate or spectator species in formic acid oxidation on a Pt film electrode Langmuir 22: 10399-408.

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●在1D Pt 原子列上，CO途径不工作，电极未出现毒化现象
●甲酸能在1D Pt 原子列上氧化, 直接途径反应电流正比于台阶密度

●直接途径以此机理进行的可能性很小

 

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